Asymmetric syntheses of 8-oxabicyclo[3,2,1]octane and 11-oxatricyclo[5.3.1.0]undecane from glycals

Herein, we describe an efficient method to prepare enantiomerically pure 8-oxabicyclo[3.2.1]octanes via gold(i)-catalyzed tandem 1,3-acyloxy migration/Ferrier rearrangement of glycal derived 1,6-enyne bearing propargylic carboxylates. The resultant compounds could then undergo interrupted Nazarov cy...

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Detalles Bibliográficos
Autores principales: Liao, Hongze, Leng, Wei-Lin, Le Mai Hoang, Kim, Yao, Hui, He, Jingxi, Voo, Amanda Ying Hui, Liu, Xue-Wei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5625258/
https://www.ncbi.nlm.nih.gov/pubmed/28989693
http://dx.doi.org/10.1039/c7sc02625k

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5625258/
https://www.ncbi.nlm.nih.gov/pubmed/28989693
http://dx.doi.org/10.1039/c7sc02625k

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