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Solid-state molecular organometallic chemistry. Single-crystal to single-crystal reactivity and catalysis with light hydrocarbon substrates

Single-crystal to single-crystal solid/gas reactivity and catalysis starting from the precursor sigma-alkane complex [Rh(Cy(2)PCH(2)CH(2)PCy(2))(η(2)η(2)-NBA)][BAr(F)(4)] (NBA = norbornane; Ar(F) = 3,5-(CF(3))(2)C(6)H(3)) is reported. By adding ethene, propene and 1-butene to this precursor in solid...

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Detalles Bibliográficos
Autores principales:	Chadwick, F. Mark, McKay, Alasdair I., Martinez-Martinez, Antonio J., Rees, Nicholas H., Krämer, Tobias, Macgregor, Stuart A., Weller, Andrew S.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2017
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5625289/ https://www.ncbi.nlm.nih.gov/pubmed/28989631 http://dx.doi.org/10.1039/c7sc01491k

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