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Improved surface-enhanced Raman and catalytic activities of reduced graphene oxide–osmium hybrid nano thin films

Reduced graphene oxide–osmium (rGO-Os) hybrid nano dendtrites have been prepared by simple liquid/liquid interface method for the first time. The method involves the introduction of phase-transfered metal organic precursor in toluene phase and GO dispersion in the aqueous phase along with hydrazine...

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Autores principales: Kavitha, C., Bramhaiah, K., John, Neena S., Aggarwal, Shantanu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society Publishing 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5627083/
https://www.ncbi.nlm.nih.gov/pubmed/28989743
http://dx.doi.org/10.1098/rsos.170353
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author Kavitha, C.
Bramhaiah, K.
John, Neena S.
Aggarwal, Shantanu
author_facet Kavitha, C.
Bramhaiah, K.
John, Neena S.
Aggarwal, Shantanu
author_sort Kavitha, C.
collection PubMed
description Reduced graphene oxide–osmium (rGO-Os) hybrid nano dendtrites have been prepared by simple liquid/liquid interface method for the first time. The method involves the introduction of phase-transfered metal organic precursor in toluene phase and GO dispersion in the aqueous phase along with hydrazine hydrate as the reducing agent. Dendritic networks of Os nanoparticles and their aggregates decorating rGO layers are obtained. The substrate shows improved catalytic and surface-enhanced activities comparable with previous reports. The catalytic activity was tested for the reduction of p-nitroaniline into p-phenyldiamine with an excess amount of NaBH(4). The catalytic activity factors of these hybrid films are 2.3 s(−1) g(−1) (Os film) and 4.4 s(−1) g(−1) (rGO-Os hybrid film), which are comparable with other noble metal nanoparticles such as Au, Ag, but lower than Pd-based catalysts. Surface-enhanced Raman spectroscopy (SERS) measurements have been done on rhodamine 6G (R6G) and methylene blue dyes. The enhancement factor for the R6G adsorbed on rGO-Os thin film is 1.0 × 10(5) and for Os thin film is 7 × 10(3). There is a 14-fold enhancement observed for Os hybrids with rGO. The enhanced catalytic and SERS activities of rGO-Os hybrid thin film prepared by simple liquid/liquid interface method open up new challenges in electrocatalytic application and SERS-based detection of biomolecules.
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spelling pubmed-56270832017-10-08 Improved surface-enhanced Raman and catalytic activities of reduced graphene oxide–osmium hybrid nano thin films Kavitha, C. Bramhaiah, K. John, Neena S. Aggarwal, Shantanu R Soc Open Sci Chemistry Reduced graphene oxide–osmium (rGO-Os) hybrid nano dendtrites have been prepared by simple liquid/liquid interface method for the first time. The method involves the introduction of phase-transfered metal organic precursor in toluene phase and GO dispersion in the aqueous phase along with hydrazine hydrate as the reducing agent. Dendritic networks of Os nanoparticles and their aggregates decorating rGO layers are obtained. The substrate shows improved catalytic and surface-enhanced activities comparable with previous reports. The catalytic activity was tested for the reduction of p-nitroaniline into p-phenyldiamine with an excess amount of NaBH(4). The catalytic activity factors of these hybrid films are 2.3 s(−1) g(−1) (Os film) and 4.4 s(−1) g(−1) (rGO-Os hybrid film), which are comparable with other noble metal nanoparticles such as Au, Ag, but lower than Pd-based catalysts. Surface-enhanced Raman spectroscopy (SERS) measurements have been done on rhodamine 6G (R6G) and methylene blue dyes. The enhancement factor for the R6G adsorbed on rGO-Os thin film is 1.0 × 10(5) and for Os thin film is 7 × 10(3). There is a 14-fold enhancement observed for Os hybrids with rGO. The enhanced catalytic and SERS activities of rGO-Os hybrid thin film prepared by simple liquid/liquid interface method open up new challenges in electrocatalytic application and SERS-based detection of biomolecules. The Royal Society Publishing 2017-09-06 /pmc/articles/PMC5627083/ /pubmed/28989743 http://dx.doi.org/10.1098/rsos.170353 Text en © 2017 The Authors. http://creativecommons.org/licenses/by/4.0/ Published by the Royal Society under the terms of the Creative Commons Attribution License http://creativecommons.org/licenses/by/4.0/, which permits unrestricted use, provided the original author and source are credited.
spellingShingle Chemistry
Kavitha, C.
Bramhaiah, K.
John, Neena S.
Aggarwal, Shantanu
Improved surface-enhanced Raman and catalytic activities of reduced graphene oxide–osmium hybrid nano thin films
title Improved surface-enhanced Raman and catalytic activities of reduced graphene oxide–osmium hybrid nano thin films
title_full Improved surface-enhanced Raman and catalytic activities of reduced graphene oxide–osmium hybrid nano thin films
title_fullStr Improved surface-enhanced Raman and catalytic activities of reduced graphene oxide–osmium hybrid nano thin films
title_full_unstemmed Improved surface-enhanced Raman and catalytic activities of reduced graphene oxide–osmium hybrid nano thin films
title_short Improved surface-enhanced Raman and catalytic activities of reduced graphene oxide–osmium hybrid nano thin films
title_sort improved surface-enhanced raman and catalytic activities of reduced graphene oxide–osmium hybrid nano thin films
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5627083/
https://www.ncbi.nlm.nih.gov/pubmed/28989743
http://dx.doi.org/10.1098/rsos.170353
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