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Preparation and characterization of chemically bonded argon–boroxol ring cation complexes
The cation complexes [ArB(3)O(4)](+), [ArB(3)O(5)](+), [ArB(4)O(6)](+) and [ArB(5)O(7)](+) were prepared via a laser vaporization supersonic ion source in the gas phase. Their vibrational spectra were measured via mass-selected infrared photodissociation spectroscopy. Spectroscopy combined with quan...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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Royal Society of Chemistry
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5627188/ https://www.ncbi.nlm.nih.gov/pubmed/28989687 http://dx.doi.org/10.1039/c7sc02472j |
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author | Jin, Jiaye Li, Wei Liu, Yuhong Wang, Guanjun Zhou, Mingfei |
author_facet | Jin, Jiaye Li, Wei Liu, Yuhong Wang, Guanjun Zhou, Mingfei |
author_sort | Jin, Jiaye |
collection | PubMed |
description | The cation complexes [ArB(3)O(4)](+), [ArB(3)O(5)](+), [ArB(4)O(6)](+) and [ArB(5)O(7)](+) were prepared via a laser vaporization supersonic ion source in the gas phase. Their vibrational spectra were measured via mass-selected infrared photodissociation spectroscopy. Spectroscopy combined with quantum chemical calculations revealed that the [ArB(3)O(5)](+), [ArB(4)O(6)](+) and [ArB(5)O(7)](+) cation complexes have planar structures each involving an aromatic boroxol ring and an argon–boron covalent bond. In contrast, the [ArB(3)O(4)](+) cation is characterized to be a weakly bound complex with a B(3)O(4) (+) chain structure. |
format | Online Article Text |
id | pubmed-5627188 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2017 |
publisher | Royal Society of Chemistry |
record_format | MEDLINE/PubMed |
spelling | pubmed-56271882017-10-06 Preparation and characterization of chemically bonded argon–boroxol ring cation complexes Jin, Jiaye Li, Wei Liu, Yuhong Wang, Guanjun Zhou, Mingfei Chem Sci Chemistry The cation complexes [ArB(3)O(4)](+), [ArB(3)O(5)](+), [ArB(4)O(6)](+) and [ArB(5)O(7)](+) were prepared via a laser vaporization supersonic ion source in the gas phase. Their vibrational spectra were measured via mass-selected infrared photodissociation spectroscopy. Spectroscopy combined with quantum chemical calculations revealed that the [ArB(3)O(5)](+), [ArB(4)O(6)](+) and [ArB(5)O(7)](+) cation complexes have planar structures each involving an aromatic boroxol ring and an argon–boron covalent bond. In contrast, the [ArB(3)O(4)](+) cation is characterized to be a weakly bound complex with a B(3)O(4) (+) chain structure. Royal Society of Chemistry 2017-09-01 2017-07-17 /pmc/articles/PMC5627188/ /pubmed/28989687 http://dx.doi.org/10.1039/c7sc02472j Text en This journal is © The Royal Society of Chemistry 2017 https://creativecommons.org/licenses/by/3.0/This is an Open Access article distributed under the terms of the Creative Commons Attribution 3.0 Unported License (http://creativecommons.org/licenses/by/3.0/ (https://creativecommons.org/licenses/by/3.0/) ) which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. |
spellingShingle | Chemistry Jin, Jiaye Li, Wei Liu, Yuhong Wang, Guanjun Zhou, Mingfei Preparation and characterization of chemically bonded argon–boroxol ring cation complexes |
title | Preparation and characterization of chemically bonded argon–boroxol ring cation complexes
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title_full | Preparation and characterization of chemically bonded argon–boroxol ring cation complexes
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title_fullStr | Preparation and characterization of chemically bonded argon–boroxol ring cation complexes
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title_full_unstemmed | Preparation and characterization of chemically bonded argon–boroxol ring cation complexes
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title_short | Preparation and characterization of chemically bonded argon–boroxol ring cation complexes
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title_sort | preparation and characterization of chemically bonded argon–boroxol ring cation complexes |
topic | Chemistry |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5627188/ https://www.ncbi.nlm.nih.gov/pubmed/28989687 http://dx.doi.org/10.1039/c7sc02472j |
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