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From imine to amine: an unexpected left turn. Cis-β iron(ii) PNNP′ precatalysts for the asymmetric transfer hydrogenation of acetophenone
A novel PNN ligand bearing an orthophenylene group and a primary amine was synthesized with the aid of a palladium-catalyzed amination and reacted with phosphonium dimers [–PR(2)CH(2)CH(OH)–](2)[Br](2) R = Et, iPr, Cy, Ph, xylyl, and o-Tol, and [Fe(OH(2))(6)](2+) to produce a new series of cis-β iro...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2017
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5627452/ https://www.ncbi.nlm.nih.gov/pubmed/28989679 http://dx.doi.org/10.1039/c7sc02558k |