Cobalt-Catalyzed [2π + 2π] Cycloadditions of Alkenes: Scope, Mechanism, and Elucidation of Electronic Structure of Catalytic Intermediates

[Image: see text] Aryl-substituted bis(imino)pyridine cobalt dinitrogen compounds, ((R)PDI)CoN(2), are effective precatalysts for the intramolecular [2π + 2π] cycloaddition of α,ω-dienes to yield the corresponding bicyclo[3.2.0]heptane derivatives. The reactions proceed under mild thermal conditions...

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Detalles Bibliográficos
Autores principales: Schmidt, Valerie A., Hoyt, Jordan M., Margulieux, Grant W., Chirik, Paul J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2015
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5633266/
https://www.ncbi.nlm.nih.gov/pubmed/26030841
http://dx.doi.org/10.1021/jacs.5b04034

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5633266/
https://www.ncbi.nlm.nih.gov/pubmed/26030841
http://dx.doi.org/10.1021/jacs.5b04034

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