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Cobalt-Catalyzed [2π + 2π] Cycloadditions of Alkenes: Scope, Mechanism, and Elucidation of Electronic Structure of Catalytic Intermediates
[Image: see text] Aryl-substituted bis(imino)pyridine cobalt dinitrogen compounds, ((R)PDI)CoN(2), are effective precatalysts for the intramolecular [2π + 2π] cycloaddition of α,ω-dienes to yield the corresponding bicyclo[3.2.0]heptane derivatives. The reactions proceed under mild thermal conditions...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2015
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5633266/ https://www.ncbi.nlm.nih.gov/pubmed/26030841 http://dx.doi.org/10.1021/jacs.5b04034 |