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Synergistic catalysis: cis-cyclopropanation of benzoxazoles

In the present paper we report our latest efforts in pushing the boundaries of synergistic catalysis. We propose the use of 3 different catalytic cycles working in concert for the formation of cis cyclopropane derivatives of benzoxazoles with excellent stereoselectivities. This is the proof of conce...

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Detalles Bibliográficos
Autores principales: Meazza, Marta, Light, Mark E., Mazzanti, Andrea, Rios, Ramon
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5633913/
https://www.ncbi.nlm.nih.gov/pubmed/29081942
http://dx.doi.org/10.1039/c5sc03597j
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author Meazza, Marta
Light, Mark E.
Mazzanti, Andrea
Rios, Ramon
author_facet Meazza, Marta
Light, Mark E.
Mazzanti, Andrea
Rios, Ramon
author_sort Meazza, Marta
collection PubMed
description In the present paper we report our latest efforts in pushing the boundaries of synergistic catalysis. We propose the use of 3 different catalytic cycles working in concert for the formation of cis cyclopropane derivatives of benzoxazoles with excellent stereoselectivities. This is the proof of concept that synergistic catalysis could be successfully used in cascade reactions.
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spelling pubmed-56339132017-10-27 Synergistic catalysis: cis-cyclopropanation of benzoxazoles Meazza, Marta Light, Mark E. Mazzanti, Andrea Rios, Ramon Chem Sci Chemistry In the present paper we report our latest efforts in pushing the boundaries of synergistic catalysis. We propose the use of 3 different catalytic cycles working in concert for the formation of cis cyclopropane derivatives of benzoxazoles with excellent stereoselectivities. This is the proof of concept that synergistic catalysis could be successfully used in cascade reactions. Royal Society of Chemistry 2016-02-01 2015-10-30 /pmc/articles/PMC5633913/ /pubmed/29081942 http://dx.doi.org/10.1039/c5sc03597j Text en This journal is © The Royal Society of Chemistry 2015 http://creativecommons.org/licenses/by/3.0/ This is an Open Access article distributed under the terms of the Creative Commons Attribution 3.0 Unported License (http://creativecommons.org/licenses/by/3.0/) which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
spellingShingle Chemistry
Meazza, Marta
Light, Mark E.
Mazzanti, Andrea
Rios, Ramon
Synergistic catalysis: cis-cyclopropanation of benzoxazoles
title Synergistic catalysis: cis-cyclopropanation of benzoxazoles
title_full Synergistic catalysis: cis-cyclopropanation of benzoxazoles
title_fullStr Synergistic catalysis: cis-cyclopropanation of benzoxazoles
title_full_unstemmed Synergistic catalysis: cis-cyclopropanation of benzoxazoles
title_short Synergistic catalysis: cis-cyclopropanation of benzoxazoles
title_sort synergistic catalysis: cis-cyclopropanation of benzoxazoles
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5633913/
https://www.ncbi.nlm.nih.gov/pubmed/29081942
http://dx.doi.org/10.1039/c5sc03597j
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