Changes in soil properties, X-ray-mineral diffractions and infrared-functional groups in bulk soil and fractions following afforestation of farmland, Northeast China

Analysis of soil properties, the compositional traits in bulk soil and different fractions and their responses to afforestation practices may possibly facilitate clarification of the mechanisms underlying soil changes. Soil properties, the compositional functional groups and minerals were determined in the bulk soil and fractions from forests and adjacent farmlands. The afforestation of farmland could induce accumulation of soil organic carbon [SOC] (+18%) and nitrogen [N] (+4%) with pH increase (+4%), and declines in electric conductivity (−15%) and bulk density (−3%). Sand and aggregates [SA] and easily oxidized fraction [EO] mainly contributed to the SOC and N accumulation. Moreover, afforestation-induced changes were observed in O-H & N-H stretching (−26%), feldspar (+52%) and huntite crystallinity (−40%). The changes of soil properties were strongly associated with the changes in functional groups, followed by minerals. Of them, asymmetric COO- & C = O stretching & O-H bending, symmetric COO- stretching, huntite and smectite-vermiculite crystallinity were the key factors responsible for the changes of soil properties. Our findings highlight that degraded farmland afforestation could strongly affect soil properties in the bulk soil, and the changes in fractions (mainly SA and EO) as well as their changes in the compositional traits strongly supported these bulk soil changes.