Shuttling single metal atom into and out of a metal nanoparticle

It has long been a challenge to dope metal nanoparticles with a specific number of heterometal atoms at specific positions. This becomes even more challenging if the heterometal belongs to the same group as the host metal because of the high tendency of forming a distribution of alloy nanoparticles with different numbers of dopants due to the similarities of metals in outmost electron configuration. Herein we report a new strategy for shuttling a single Ag or Cu atom into a centrally hollow, rod-shaped Au(24) nanoparticle, forming AgAu(24) and CuAu(24) nanoparticles in a highly controllable manner. Through a combined approach of experiment and theory, we explain the shuttling pathways of single dopants into and out of the nanoparticles. This study shows that the single dopant is shuttled into the hollow Au(24) nanoparticle either through the apex or side entry, while shuttling a metal atom out of the Au(25) to form the Au(24) nanoparticle occurs mainly through the side entry.