Raman Spectra and Bulk Modulus of Nanodiamond in a Size Interval of 2–5 nm

Nanodiamond in a 2–5-nm size interval (which is typical for an appearance of quantum confinement effect) show Raman spectra composed of 3 bands at 1325, 1600, and 1500 cm(−1) (at the 458-nm laser excitation) which shifts to 1630 cm(−1) at the 257-nm laser excitation. Contrary to sp(2)-bonded carbon, relative intensities of the bands do not depend on the 458- and 257-nm excitation wavelengths, and a halfwidth and the intensity of the 1600 cm(−1) band does not change visibly under pressure at least up to 50 GPa. Bulk modulus of the 2–5-nm nanodiamond determined from the high-pressure study is around 560 GPa. Studied 2–5-nm nanodiamond was purified from contamination layers and dispersed in Si or NaCl.