Cargando…
Synthetic control and empirical prediction of redox potentials for Co(4)O(4) cubanes over a 1.4 V range: implications for catalyst design and evaluation of high-valent intermediates in water oxidation
The oxo-cobalt cubane unit [Co(4)O(4)] is of interest as a homogeneous oxygen-evolution reaction (OER) catalyst, and as a functional mimic of heterogeneous cobalt oxide OER catalysts. The synthesis of several new cubanes allows evaluation of redox potentials for the [Co(4)O(4)] cluster, which are hi...
| Autores principales: | , , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2017
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5635813/ https://www.ncbi.nlm.nih.gov/pubmed/29081963 http://dx.doi.org/10.1039/c7sc00627f |