Cargando…

Synthetic control and empirical prediction of redox potentials for Co(4)O(4) cubanes over a 1.4 V range: implications for catalyst design and evaluation of high-valent intermediates in water oxidation

The oxo-cobalt cubane unit [Co(4)O(4)] is of interest as a homogeneous oxygen-evolution reaction (OER) catalyst, and as a functional mimic of heterogeneous cobalt oxide OER catalysts. The synthesis of several new cubanes allows evaluation of redox potentials for the [Co(4)O(4)] cluster, which are hi...

Descripción completa

Detalles Bibliográficos
Autores principales: Nguyen, Andy I., Wang, Jianing, Levine, Daniel S., Ziegler, Micah S., Tilley, T. Don
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5635813/
https://www.ncbi.nlm.nih.gov/pubmed/29081963
http://dx.doi.org/10.1039/c7sc00627f

Ejemplares similares