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α-Perfluoroalkyl-β-alkynylation of alkenes via radical alkynyl migration

Transition metal-free radical α-perfluoroalkylation with concomitant β-alkynylation of unactivated alkenes is presented. These cascades proceed via electron-catalysis and comprise a radical 1,4- or 1,5-alkynyl migration from tertiary propargylic alcoholates to secondary or tertiary C-radicals as the...

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Detalles Bibliográficos
Autores principales: Tang, Xinjun, Studer, Armido
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5637125/
https://www.ncbi.nlm.nih.gov/pubmed/29147514
http://dx.doi.org/10.1039/c7sc02175e

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