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A complementary pair of enantioselective switchable organocatalysts

A pair of enantioselective switchable bifunctional catalysts are shown to promote a range of conjugate addition reactions in up to 95 : 5 e.r. and 95% conversion. Each catalyst can be switched OFF using conditions that switch the other catalyst ON. Catalyst ON : OFF ratios of up to 98 : 2 and 1 : 99...

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Detalles Bibliográficos
Autores principales:	De Bo, Guillaume, Leigh, David A., McTernan, Charlie T., Wang, Shoufeng
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2017
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5637462/ https://www.ncbi.nlm.nih.gov/pubmed/29147536 http://dx.doi.org/10.1039/c7sc02462b

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