Metalloradical Reactivity of Ru(I) and Ru(0) Stabilized by an Indole‐Based Tripodal Tetraphosphine Ligand

The tripodal, tetradentate tris(1‐(diphenylphosphanyl)‐3‐methyl‐1H‐indol‐2‐yl)phosphane PP(3)‐ligand 1 stabilizes Ru in the Ru(II), Ru(I), and Ru(0) oxidation states. The octahedral [(PP(3))Ru(II)(Cl)(2)] (2), distorted trigonal bipyramidal [(PP(3))Ru(I)(Cl)] (3), and trigonal bipyramidal [(PP(3))Ru...

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Detalles Bibliográficos
Autores principales: van de Watering, Fenna F., van der Vlugt, Jarl Ivar, Dzik, Wojciech I., de Bruin, Bas, Reek, Joost N. H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2017
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5639366/
https://www.ncbi.nlm.nih.gov/pubmed/28857278
http://dx.doi.org/10.1002/chem.201702727
Descripción
Sumario:The tripodal, tetradentate tris(1‐(diphenylphosphanyl)‐3‐methyl‐1H‐indol‐2‐yl)phosphane PP(3)‐ligand 1 stabilizes Ru in the Ru(II), Ru(I), and Ru(0) oxidation states. The octahedral [(PP(3))Ru(II)(Cl)(2)] (2), distorted trigonal bipyramidal [(PP(3))Ru(I)(Cl)] (3), and trigonal bipyramidal [(PP(3))Ru(0)(N(2))] (4) complexes were isolated and characterized by single‐crystal X‐ray diffraction, NMR, EPR, IR, and ESI‐MS. Both open‐shell metalloradical Ru(I) complex 3 and the closed‐shell Ru(0) complex 4 undergo facile (net) abstraction of a Cl atom from dichloromethane, resulting in formation of the corresponding Ru(II) and Ru(I) complexes 2 and 3, respectively.

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