Competing Pathways in O‐Arylations with Diaryliodonium Salts: Mechanistic Insights

A mechanistic study of arylations of aliphatic alcohols and hydroxide with diaryliodonium salts, to give alkyl aryl ethers and diaryl ethers, has been performed using experimental techniques and DFT calculations. Aryne intermediates have been trapped, and additives to avoid by‐product formation orig...

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Detalles Bibliográficos
Autores principales: Stridfeldt, Elin, Lindstedt, Erik, Reitti, Marcus, Blid, Jan, Norrby, Per‐Ola, Olofsson, Berit
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2017
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5639379/
https://www.ncbi.nlm.nih.gov/pubmed/28792102
http://dx.doi.org/10.1002/chem.201703057

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5639379/
https://www.ncbi.nlm.nih.gov/pubmed/28792102
http://dx.doi.org/10.1002/chem.201703057

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