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Remote C–H insertion of vinyl cations leading to cyclopentenones

We report a Lewis acid catalyzed reaction sequence involving a 1,2-shift and subsequent C–H insertion that gives monocyclic and fused bicyclic cyclopentenone products. This reaction sequence, which is initiated by treating β-hydroxy-α-diazo ketones with a Lewis acid, proceeds through vinyl cation in...

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Detalles Bibliográficos
Autores principales: Cleary, Sarah E., Hensinger, Magenta J., Brewer, Matthias
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5643953/
https://www.ncbi.nlm.nih.gov/pubmed/29147505
http://dx.doi.org/10.1039/c7sc02768k

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