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Mechanism, reactivity, and selectivity of the iridium-catalyzed C(sp(3))–H borylation of chlorosilanes
The iridium-catalyzed C(sp(3))–H borylation of methylchlorosilanes is investigated by means of density functional theory, using the B3LYP and M06 functionals. The calculations establish that the resting state of the catalyst is a seven-coordinate Ir(v) species that has to be converted into an Ir(iii...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2015
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5644124/ https://www.ncbi.nlm.nih.gov/pubmed/29163873 http://dx.doi.org/10.1039/c4sc01592d |