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Fabrication of AO/LDH fluorescence composite and its detection of Hg(2+) in water
Divalent mercury ion (Hg(2+)) is one of the most common pollutants in water with high toxicity and significant bioaccumulation, for which sensitive and selective detection methods are highly necessary to carry out its detection and quantification. Fluorescence detection by organic dyes is a simple a...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group UK
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5645344/ https://www.ncbi.nlm.nih.gov/pubmed/29042613 http://dx.doi.org/10.1038/s41598-017-13779-1 |
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author | Liu, Meng Lv, Guocheng Mei, Lefu Wei, Yanke Liu, Jieyuan Li, Zhaohui Liao, Libing |
author_facet | Liu, Meng Lv, Guocheng Mei, Lefu Wei, Yanke Liu, Jieyuan Li, Zhaohui Liao, Libing |
author_sort | Liu, Meng |
collection | PubMed |
description | Divalent mercury ion (Hg(2+)) is one of the most common pollutants in water with high toxicity and significant bioaccumulation, for which sensitive and selective detection methods are highly necessary to carry out its detection and quantification. Fluorescence detection by organic dyes is a simple and rapid method in pollutant analyses and is limited because of quenching caused by aggregation dye molecules. Hydrotalcite (LDH) is one of the most excellent carrier materials. In this study, an organic dye acridine orange (AO) was successfully loaded on the LDH layers, which significantly inhibited fluorescence quenching of AO. The composite AO/LDH reaches the highest fluorescence intensity when the AO initial concentration is 5 mg/L. With its enhanced fluorescent property, the composite powder was fabricated to fluorescence test papers. The maximal fluorescence intensity was achieved with a pulp to AO/LDH ratio of 1:5 which can be used to detect Hg(2+) in water by naked eyes. Hg(2+) in aqueous solution can be detected by instruments in the range of 0.5 to 150 mM. The novelty of this study lies on both the development of a new type of mineral-dye composite material, as well as its practical applications for fast detection. |
format | Online Article Text |
id | pubmed-5645344 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2017 |
publisher | Nature Publishing Group UK |
record_format | MEDLINE/PubMed |
spelling | pubmed-56453442017-10-26 Fabrication of AO/LDH fluorescence composite and its detection of Hg(2+) in water Liu, Meng Lv, Guocheng Mei, Lefu Wei, Yanke Liu, Jieyuan Li, Zhaohui Liao, Libing Sci Rep Article Divalent mercury ion (Hg(2+)) is one of the most common pollutants in water with high toxicity and significant bioaccumulation, for which sensitive and selective detection methods are highly necessary to carry out its detection and quantification. Fluorescence detection by organic dyes is a simple and rapid method in pollutant analyses and is limited because of quenching caused by aggregation dye molecules. Hydrotalcite (LDH) is one of the most excellent carrier materials. In this study, an organic dye acridine orange (AO) was successfully loaded on the LDH layers, which significantly inhibited fluorescence quenching of AO. The composite AO/LDH reaches the highest fluorescence intensity when the AO initial concentration is 5 mg/L. With its enhanced fluorescent property, the composite powder was fabricated to fluorescence test papers. The maximal fluorescence intensity was achieved with a pulp to AO/LDH ratio of 1:5 which can be used to detect Hg(2+) in water by naked eyes. Hg(2+) in aqueous solution can be detected by instruments in the range of 0.5 to 150 mM. The novelty of this study lies on both the development of a new type of mineral-dye composite material, as well as its practical applications for fast detection. Nature Publishing Group UK 2017-10-17 /pmc/articles/PMC5645344/ /pubmed/29042613 http://dx.doi.org/10.1038/s41598-017-13779-1 Text en © The Author(s) 2017 Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/. |
spellingShingle | Article Liu, Meng Lv, Guocheng Mei, Lefu Wei, Yanke Liu, Jieyuan Li, Zhaohui Liao, Libing Fabrication of AO/LDH fluorescence composite and its detection of Hg(2+) in water |
title | Fabrication of AO/LDH fluorescence composite and its detection of Hg(2+) in water |
title_full | Fabrication of AO/LDH fluorescence composite and its detection of Hg(2+) in water |
title_fullStr | Fabrication of AO/LDH fluorescence composite and its detection of Hg(2+) in water |
title_full_unstemmed | Fabrication of AO/LDH fluorescence composite and its detection of Hg(2+) in water |
title_short | Fabrication of AO/LDH fluorescence composite and its detection of Hg(2+) in water |
title_sort | fabrication of ao/ldh fluorescence composite and its detection of hg(2+) in water |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5645344/ https://www.ncbi.nlm.nih.gov/pubmed/29042613 http://dx.doi.org/10.1038/s41598-017-13779-1 |
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