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Rhodium-catalyzed C–H functionalization-based approach to eight-membered lactams

A Rh(iii) catalyzed formal [4 + 2 + 2] cyclization of N-pivaloyloxybenzamides 1 with 1,6-allene-enes 2 by C–H functionalization is reported. The reactions occur at room temperature and are compatible with air and moisture with a tolerance of many synthetically useful functional groups. The follow-up...

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Detalles Bibliográficos
Autores principales:	Wu, Shangze, Zeng, Rong, Fu, Chunling, Yu, Yihua, Zhang, Xue, Ma, Shengming
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2015
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5645731/ https://www.ncbi.nlm.nih.gov/pubmed/29308141 http://dx.doi.org/10.1039/c5sc00092k

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