Extending N-heterocyclic carbene ligands into the third dimension: a new type of hybrid phosphazane/NHC system

A simple, “click” synthetic approach to a new type of hybrid phosph(III)azane/NHC system is described. The presence of the phosphazane P(2)N(2) ring unit, with P atoms flanking the NCN fragment and with this ring perpendicular to the binding site of the NHC, provides unique opportunities for modifyi...

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Detalles Bibliográficos
Autores principales: Roth, Torsten, Vasilenko, Vladislav, Benson, Callum G. M., Wadepohl, Hubert, Wright, Dominic S., Gade, Lutz H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5647813/
https://www.ncbi.nlm.nih.gov/pubmed/29308160
http://dx.doi.org/10.1039/c4sc03966a
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author Roth, Torsten
Vasilenko, Vladislav
Benson, Callum G. M.
Wadepohl, Hubert
Wright, Dominic S.
Gade, Lutz H.
author_facet Roth, Torsten
Vasilenko, Vladislav
Benson, Callum G. M.
Wadepohl, Hubert
Wright, Dominic S.
Gade, Lutz H.
author_sort Roth, Torsten
collection PubMed
description A simple, “click” synthetic approach to a new type of hybrid phosph(III)azane/NHC system is described. The presence of the phosphazane P(2)N(2) ring unit, with P atoms flanking the NCN fragment and with this ring perpendicular to the binding site of the NHC, provides unique opportunities for modifying the electronic and steric character of these carbenes.
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spelling pubmed-56478132018-01-05 Extending N-heterocyclic carbene ligands into the third dimension: a new type of hybrid phosphazane/NHC system Roth, Torsten Vasilenko, Vladislav Benson, Callum G. M. Wadepohl, Hubert Wright, Dominic S. Gade, Lutz H. Chem Sci Chemistry A simple, “click” synthetic approach to a new type of hybrid phosph(III)azane/NHC system is described. The presence of the phosphazane P(2)N(2) ring unit, with P atoms flanking the NCN fragment and with this ring perpendicular to the binding site of the NHC, provides unique opportunities for modifying the electronic and steric character of these carbenes. Royal Society of Chemistry 2015-04-01 2015-02-13 /pmc/articles/PMC5647813/ /pubmed/29308160 http://dx.doi.org/10.1039/c4sc03966a Text en This journal is © The Royal Society of Chemistry 2015 http://creativecommons.org/licenses/by/3.0/ This is an Open Access article distributed under the terms of the Creative Commons Attribution 3.0 Unported License (http://creativecommons.org/licenses/by/3.0/) which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
spellingShingle Chemistry
Roth, Torsten
Vasilenko, Vladislav
Benson, Callum G. M.
Wadepohl, Hubert
Wright, Dominic S.
Gade, Lutz H.
Extending N-heterocyclic carbene ligands into the third dimension: a new type of hybrid phosphazane/NHC system
title Extending N-heterocyclic carbene ligands into the third dimension: a new type of hybrid phosphazane/NHC system
title_full Extending N-heterocyclic carbene ligands into the third dimension: a new type of hybrid phosphazane/NHC system
title_fullStr Extending N-heterocyclic carbene ligands into the third dimension: a new type of hybrid phosphazane/NHC system
title_full_unstemmed Extending N-heterocyclic carbene ligands into the third dimension: a new type of hybrid phosphazane/NHC system
title_short Extending N-heterocyclic carbene ligands into the third dimension: a new type of hybrid phosphazane/NHC system
title_sort extending n-heterocyclic carbene ligands into the third dimension: a new type of hybrid phosphazane/nhc system
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5647813/
https://www.ncbi.nlm.nih.gov/pubmed/29308160
http://dx.doi.org/10.1039/c4sc03966a
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