Cargando…

Extending N-heterocyclic carbene ligands into the third dimension: a new type of hybrid phosphazane/NHC system

A simple, “click” synthetic approach to a new type of hybrid phosph(III)azane/NHC system is described. The presence of the phosphazane P(2)N(2) ring unit, with P atoms flanking the NCN fragment and with this ring perpendicular to the binding site of the NHC, provides unique opportunities for modifyi...

Descripción completa

Detalles Bibliográficos
Autores principales:	Roth, Torsten, Vasilenko, Vladislav, Benson, Callum G. M., Wadepohl, Hubert, Wright, Dominic S., Gade, Lutz H.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2015
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5647813/ https://www.ncbi.nlm.nih.gov/pubmed/29308160 http://dx.doi.org/10.1039/c4sc03966a

Ejemplares similares

Energy transfer (EnT) photocatalysis enabled by gold-N-heterocyclic carbene (NHC) complexes
por: Martynova, Ekaterina A., et al.
Publicado: (2022)

Recent advances in N-heterocyclic carbene (NHC)-catalysed benzoin reactions
por: Menon, Rajeev S, et al.
Publicado: (2016)

A modular approach to neutral P,N-ligands: synthesis and coordination chemistry
por: Vasilenko, Vladislav, et al.
Publicado: (2016)

Correction: Recent advances in N-heterocyclic carbene (NHC)-catalysed benzoin reactions
por: Menon, Rajeev S, et al.
Publicado: (2016)

A general synthetic route to [Cu(X)(NHC)] (NHC = N-heterocyclic carbene, X = Cl, Br, I) complexes
por: Santoro, Orlando, et al.
Publicado: (2013)

Reaction Pathways and Redox States in α‐Selective Cobalt‐Catalyzed Hydroborations of Alkynes
por: Blasius, Clemens K., et al.
Publicado: (2020)

4-Alkylated Silver–N-Heterocyclic Carbene (NHC) Complexes with Cytotoxic Effects in Leukemia Cells
por: Sandtorv, Alexander H, et al.
Publicado: (2015)

N-Heterocyclic carbene–carbodiimide (NHC–CDI) betaine adducts: synthesis, characterization, properties, and applications
por: Lamb, Jessica R., et al.
Publicado: (2021)

Electrolyte tuning in dye-sensitized solar cells with N-heterocyclic carbene (NHC) iron(II) sensitizers
por: Karpacheva, Mariia, et al.
Publicado: (2018)

N‐Heterocyclic Carbene (NHC) Silver Complexes as Versatile Chemotherapeutic Agents Targeting Human Topoisomerases and Actin
por: Mariconda, Annaluisa, et al.
Publicado: (2022)

A Redox‐Active Heterobimetallic N‐Heterocyclic Carbene Based on a Bis(imino)pyrazine Ligand Scaffold
por: Regenauer, Nicolas I., et al.
Publicado: (2020)

[IPr(#)–PEPPSI]: A Well-Defined, Highly Hindered and Broadly Applicable Pd(II)–NHC (NHC = N-Heterocyclic Carbene) Precatalyst for Cross-Coupling Reactions
por: Rahman, Md. Mahbubur, et al.
Publicado: (2023)

A chiral phosphazane reagent strategy for the determination of enantiomeric excess of amines
por: Peel, Andrew J., et al.
Publicado: (2022)

Azaphilic versus Carbophilic Coupling at C=N Bonds: Key Steps in Titanium‐Assisted Multicomponent Reactions
por: Roth, Torsten, et al.
Publicado: (2015)

N-Heterocyclic carbene (NHC)-catalyzed oxidation of unactivated aldimines to amides via imine umpolung under aerobic conditions
por: Ramarao, Jakkula, et al.
Publicado: (2022)

The effects of two gold-N-heterocyclic carbene (NHC) complexes in ovarian cancer cells: a redox proteomic study
por: Massai, Lara, et al.
Publicado: (2022)

Extending the utility of [Pd(NHC)(cinnamyl)Cl] precatalysts: Direct arylation of heterocycles
por: Martin, Anthony R, et al.
Publicado: (2012)

N-Heterocyclic carbenes
por: Nolan, Steven P
Publicado: (2015)

N‐Heterocyclic Carbene Organocatalysis: With or Without Carbenes?
por: Gehrke, Sascha, et al.
Publicado: (2020)

The boron–boron triple bond? A thermodynamic and force field based interpretation of the N-heterocyclic carbene (NHC) stabilization procedure
por: Köppe, R., et al.
Publicado: (2015)

Possible Synthetic Approaches for Heterobimetallic Complexes by Using nNHC/tzNHC Heteroditopic Carbene Ligands
por: Longhi, Andrea, et al.
Publicado: (2019)

A (TD-)DFT study on photo-NHC catalysis: photoenolization/Diels–Alder reaction of acid fluorides catalyzed by N-heterocyclic carbenes
por: Mavroskoufis, Andreas, et al.
Publicado: (2023)

The reaction of rhenium nitrosyl with a sterically hindered NHC-carbene
por: Grieco, G., et al.
Publicado: (2022)

Facile H/D Exchange at (Hetero)Aromatic Hydrocarbons Catalyzed by a Stable Trans-Dihydride N-Heterocyclic Carbene (NHC) Iron Complex
por: Garhwal, Subhash, et al.
Publicado: (2020)

Porphyrins and Metalloporphyrins Combined with N-Heterocyclic Carbene (NHC) Gold(I) Complexes for Photodynamic Therapy Application: What Is the Weight of the Heavy Atom Effect?
por: Scoditti, Stefano, et al.
Publicado: (2022)

p53-Dependent Anti-Proliferative and Pro-Apoptotic Effects of a Gold(I) N-Heterocyclic Carbene (NHC) Complex in Colorectal Cancer Cells
por: Dabiri, Yasamin, et al.
Publicado: (2019)

Oxidative N‐Heterocyclic Carbene Catalysis
por: De Risi, Carmela, et al.
Publicado: (2022)

Halogen Complexes of Anionic N‐Heterocyclic Carbenes
por: Frosch, Jenni, et al.
Publicado: (2020)

Actinide tetra-N-heterocyclic carbene ‘sandwiches’
por: DeJesus, Joseph F., et al.
Publicado: (2021)

N-Heterocyclic carbene-based gold etchants
por: Chevalier, Robert B, et al.
Publicado: (2023)

MOF-Zn-NHC as an efficient N-heterocyclic carbene catalyst for aerobic oxidation of aldehydes to their corresponding carboxylic acids via a cooperative geminal anomeric based oxidation
por: Babaee, Saeed, et al.
Publicado: (2021)

Structural and Luminescent Properties of Homoleptic Silver(I), Gold(I), and Palladium(II) Complexes with nNHC-tzNHC Heteroditopic Carbene Ligands
por: Monticelli, Marco, et al.
Publicado: (2019)

Size-control in the synthesis of oxo-bridged phosphazane macrocycles via a modular addition approach
por: Shi, Xiaoyan, et al.
Publicado: (2021)

Metal-NHC heterocycle complexes in catalysis and biological applications: Systematic review
por: Jalal, Mohammed, et al.
Publicado: (2020)

Crystal structure of bis(1,3-dimethoxyimidazolin-2-ylidene)silver(I) hexafluoridophosphate, N-heterocyclic carbene (NHC) complex
por: Rietzler, Barbara, et al.
Publicado: (2015)

A Ruthenium(II) N-Heterocyclic Carbene (NHC) Complex with Naphthalimide Ligand Triggers Apoptosis in Colorectal Cancer Cells via Activating the ROS-p38 MAPK Pathway
por: Dabiri, Yasamin, et al.
Publicado: (2018)

Alkyne hydroarylation with Au N-heterocyclic carbene catalysts
por: Tubaro, Cristina, et al.
Publicado: (2013)

Self-Supported N-Heterocyclic Carbenes and Their Use as Organocatalysts
por: Ma, Shuang, et al.
Publicado: (2016)

Functionalised N‐Heterocyclic Carbene Ligands in Bimetallic Architectures
por: Evans, Kieren J., et al.
Publicado: (2020)

Cooperation of N‐Heterocyclic Carbenes on a Gold Surface
por: Amirjalayer, Saeed, et al.
Publicado: (2020)

Cannot write session to /tmp/vufind_sessions/sess_b3hqadsjprpv70q36hetqvat6a