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C–H arylation of triphenylene, naphthalene and related arenes using Pd/C
A highly selective arylation of a number of polyaromatic hydrocarbons (PAHs) with aryliodonium salts and Pd/C as the only reagent is reported. The first C–H functionalization of triphenylene is explored, and proceeds at the most sterically hindered position. This non-chelate assisted C–H functionali...
Autores principales: | Collins, Karl D., Honeker, Roman, Vásquez-Céspedes, Suhelen, Tang, Dan-Tam D., Glorius, Frank |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5649329/ https://www.ncbi.nlm.nih.gov/pubmed/29308135 http://dx.doi.org/10.1039/c4sc03051f |
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