Electrodeposition of tin on Nafion-bonded carbon black as an active catalyst layer for efficient electroreduction of CO(2) to formic acid

Electroreduction of CO(2) to formic acid (ERCF) based on gas diffusion electrodes (GDEs) has been considered as a promising method to convert CO(2) into value-added chemicals. However, current GDEs for ERCF suffer from low efficiency of electron transfer. In this work, a novel Sn-based gas diffusion electrode (ESGDE) is prepared by electrodepositing Sn on Nafion-bonded carbon black as catalyst layer to enhance electron transfer and thus the efficiency of ERCF. The highest Faraday efficiency (73.01 ± 3.42%), current density (34.21 ± 1.14 mA cm(−2)) and production rate (1772.81 ± 59.08 μmol m(−2) s(−1)) of formic acid are obtained by using the ESGDE with electrodeposition time of 90 s in 0.5 M KHCO(3) solution, which are one of the highest values obtained from Sn-based gas diffusion electrodes under similar conditions. The notable efficiency of ERCF achieved here should be attributed to the enhancement in the reactants transfer as well as the three-dimensional reaction zone. This work will be helpful for the industrial application of GDEs in EFCF.