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Bimetallic lanthanide complexes that display a ratiometric response to oxygen concentrations

A pair of hetero-bimetallic lanthanide complexes containing terbium and europium ions have been prepared by coupling kinetically stable complexes together using an Ugi methodology to incorporate a naphthyl chromophore. Both complexes exhibit emission from terbium and europium in solution. The terbiu...

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Detalles Bibliográficos
Autores principales: Sørensen, Thomas Just, Kenwright, Alan M., Faulkner, Stephen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5654241/
https://www.ncbi.nlm.nih.gov/pubmed/29142674
http://dx.doi.org/10.1039/c4sc03827d
Descripción
Sumario:A pair of hetero-bimetallic lanthanide complexes containing terbium and europium ions have been prepared by coupling kinetically stable complexes together using an Ugi methodology to incorporate a naphthyl chromophore. Both complexes exhibit emission from terbium and europium in solution. The terbium centred emission varies with dissolved oxygen concentration, while the europium intensity remains essentially constant in one of the complexes.