Bimetallic lanthanide complexes that display a ratiometric response to oxygen concentrations

A pair of hetero-bimetallic lanthanide complexes containing terbium and europium ions have been prepared by coupling kinetically stable complexes together using an Ugi methodology to incorporate a naphthyl chromophore. Both complexes exhibit emission from terbium and europium in solution. The terbiu...

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Detalles Bibliográficos
Autores principales: Sørensen, Thomas Just, Kenwright, Alan M., Faulkner, Stephen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5654241/
https://www.ncbi.nlm.nih.gov/pubmed/29142674
http://dx.doi.org/10.1039/c4sc03827d
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author Sørensen, Thomas Just
Kenwright, Alan M.
Faulkner, Stephen
author_facet Sørensen, Thomas Just
Kenwright, Alan M.
Faulkner, Stephen
author_sort Sørensen, Thomas Just
collection PubMed
description A pair of hetero-bimetallic lanthanide complexes containing terbium and europium ions have been prepared by coupling kinetically stable complexes together using an Ugi methodology to incorporate a naphthyl chromophore. Both complexes exhibit emission from terbium and europium in solution. The terbium centred emission varies with dissolved oxygen concentration, while the europium intensity remains essentially constant in one of the complexes.
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spelling pubmed-56542412017-11-15 Bimetallic lanthanide complexes that display a ratiometric response to oxygen concentrations Sørensen, Thomas Just Kenwright, Alan M. Faulkner, Stephen Chem Sci Chemistry A pair of hetero-bimetallic lanthanide complexes containing terbium and europium ions have been prepared by coupling kinetically stable complexes together using an Ugi methodology to incorporate a naphthyl chromophore. Both complexes exhibit emission from terbium and europium in solution. The terbium centred emission varies with dissolved oxygen concentration, while the europium intensity remains essentially constant in one of the complexes. Royal Society of Chemistry 2015-03-01 2015-01-12 /pmc/articles/PMC5654241/ /pubmed/29142674 http://dx.doi.org/10.1039/c4sc03827d Text en This journal is © The Royal Society of Chemistry 2015 http://creativecommons.org/licenses/by/3.0/ This is an Open Access article distributed under the terms of the Creative Commons Attribution 3.0 Unported License (http://creativecommons.org/licenses/by/3.0/) which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
spellingShingle Chemistry
Sørensen, Thomas Just
Kenwright, Alan M.
Faulkner, Stephen
Bimetallic lanthanide complexes that display a ratiometric response to oxygen concentrations
title Bimetallic lanthanide complexes that display a ratiometric response to oxygen concentrations
title_full Bimetallic lanthanide complexes that display a ratiometric response to oxygen concentrations
title_fullStr Bimetallic lanthanide complexes that display a ratiometric response to oxygen concentrations
title_full_unstemmed Bimetallic lanthanide complexes that display a ratiometric response to oxygen concentrations
title_short Bimetallic lanthanide complexes that display a ratiometric response to oxygen concentrations
title_sort bimetallic lanthanide complexes that display a ratiometric response to oxygen concentrations
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5654241/
https://www.ncbi.nlm.nih.gov/pubmed/29142674
http://dx.doi.org/10.1039/c4sc03827d
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