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The gold(i)···lead(ii) interaction: a relativistic connection
The crystal structure of complex [Pb{HB(pz)(3)}Au(C(6)Cl(5))(2)] 1 displays an unsupported Au(i)···Pb(ii) interaction. This complex emits at 480 nm in the solid state due to an aurate(i) to lead(ii) charge transfer, in which the existence of a metallophilic interaction is a pre-requisite. Ab initio...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2015
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5654245/ https://www.ncbi.nlm.nih.gov/pubmed/29142670 http://dx.doi.org/10.1039/c4sc03680h |