Cargando…

Remote functionalization of hydrocarbons with reversibility enhanced stereocontrol

Remote functionalization of hydrocarbons could be achieved through successive zirconocene-mediated allylic C–H bond activations followed by a selective C–C bond cleavage. Determination of the reaction mechanism by density functional theory (DFT) calculations shows that the high stereocontrol observe...

Descripción completa

Detalles Bibliográficos
Autores principales:	Vasseur, Alexandre, Perrin, Lionel, Eisenstein, Odile, Marek, Ilan
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2015
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5654413/ https://www.ncbi.nlm.nih.gov/pubmed/29142680 http://dx.doi.org/10.1039/c5sc00445d

Ejemplares similares

Stereocontrolled semi-syntheses of deguelin and tephrosin
por: Russell, David A., et al.
Publicado: (2017)

Stereocontrolled synthesis of some novel functionalized heterocyclic amino ester and amide derivatives with multiple stereocenters
por: Semghouli, Anas, et al.
Publicado: (2023)

Stereocontrolled protein surface recognition using chiral oligoamide proteomimetic foldamers
por: Azzarito, Valeria, et al.
Publicado: (2015)

Role of imine isomerization in the stereocontrol of the Staudinger reaction between ketenes and imines
por: Cossío, Fernando P., et al.
Publicado: (2021)

Stereocontrolled addition of Grignard reagents to oxa-bridged benzazepines: highly efficient synthesis of functionalized benzazepine scaffolds
por: Zhang, Yuewei, et al.
Publicado: (2020)

Sugar silanes: versatile reagents for stereocontrolled glycosylation via intramolecular aglycone delivery
por: Walk, Jordan T., et al.
Publicado: (2015)

Photocatalyst-independent photoredox ring-opening polymerization of O-carboxyanhydrides: stereocontrol and mechanism
por: Zhong, Yongliang, et al.
Publicado: (2021)

Stereocontrolled Synthesis and Functionalization of Cyclobutanes and Cyclobutanones
por: Secci, Francesco, et al.
Publicado: (2013)

Stereocontrolled 1,2-cis glycosylation as the driving force of progress in synthetic carbohydrate chemistry
por: Nigudkar, Swati S., et al.
Publicado: (2015)

Interrogating the thionium hydrogen bond as a noncovalent stereocontrolling interaction in chiral phosphate catalysis
por: Lai, Junshan, et al.
Publicado: (2022)

Solid-phase synthesis and properties of stereocontrolled boranophosphate/phosphate and phosphorothioate/phosphate chimeric oligouridylates
por: Sato, Kazuki, et al.
Publicado: (2023)

Re-orienting coupling of organocuprates with propargyl electrophiles from S(N)2′ to S(N)2 with stereocontrol
por: Trost, Barry M., et al.
Publicado: (2016)

P-stereocontrolled synthesis of oligo(nucleoside N3′→O5′ phosphoramidothioate)s – opportunities and limitations
por: Radzikowska, Ewa, et al.
Publicado: (2020)

Stereocontrolled access to δ-lactone-fused-γ-lactams bearing angular benzylic quaternary stereocenters
por: Beng, Timothy K., et al.
Publicado: (2022)

Elucidation of the stereocontrol mechanisms of the chemical and biosynthetic intramolecular Diels–Alder cycloaddition for the formation of bioactive decalins
por: Kariya, Takumi, et al.
Publicado: (2023)

Stereocontrolled Total Synthesis of (−)‐Stemaphylline
por: Varela, Ana, et al.
Publicado: (2017)

Chiral hybrid materials based on pyrrolidine building units to perform asymmetric Michael additions with high stereocontrol
por: Llopis, Sebastián, et al.
Publicado: (2018)

Enantioselective catalytic β-amination through proton-coupled electron transfer followed by stereocontrolled radical–radical coupling
por: Zhou, Zijun, et al.
Publicado: (2017)

Catalytic, selective, and stereocontrolled construction of C4 quaternary and homobenzylic dihydroisoquinolones by sp(3) C–H benzylation
por: Beng, Timothy K., et al.
Publicado: (2020)

A unique Pd-catalysed Heck arylation as a remote trigger for cyclopropane selective ring-opening
por: Singh, Sukhdev, et al.
Publicado: (2017)

Novel stereocontrolled syntheses of tashiromine and epitashiromine
por: Kiss, Loránd, et al.
Publicado: (2015)

On the proposed structures and stereocontrolled synthesis of the cephalosporolides
por: Tlais, Sami F, et al.
Publicado: (2012)

Simple, Chemoselective Hydrogenation with Thermodynamic Stereocontrol
por: Iwasaki, Kotaro, et al.
Publicado: (2014)

Aminodiols via Stereocontrolled Oxidation of Methyleneaziridines
por: Rigoli, Jared W., et al.
Publicado: (2014)

Inverted stereocontrol of iridoid synthase in snapdragon
por: Kries, Hajo, et al.
Publicado: (2017)

Cu/Pd-catalyzed arylboration of a 1-silyl-1,3-cyclohexadiene for stereocontrolled and diverse cyclohexane/ene synthesis
por: Crook, Phillip F., et al.
Publicado: (2023)

Organocatalytic one-pot 1,4-/1,6-/1,2-addition sequence for the stereocontrolled formation of six consecutive stereocenters
por: Chauhan, Pankaj, et al.
Publicado: (2015)

A thiocyanopalladation/carbocyclization transformation identified through enzymatic screening: stereocontrolled tandem C–SCN and C–C bond formation
por: Malik, G., et al.
Publicado: (2017)

Cyclization of interlocked fumaramides into β-lactams: experimental and computational mechanistic assessment of the key intercomponent proton transfer and the stereocontrolling active pocket
por: Martinez-Cuezva, Alberto, et al.
Publicado: (2020)

Metal-free alkene carbooxygenation following tandem intramolecular alkoxylation/Claisen rearrangement: stereocontrolled access to bridged [4.2.1] lactones
por: Li, Long, et al.
Publicado: (2019)

Contra-thermodynamic halolactonization of lactam-tethered 5-aryl-4(E)-pentenoic acids for the flexible and stereocontrolled synthesis of fused lactam-halolactones
por: Beng, Timothy K., et al.
Publicado: (2022)

Stereocontrolled Synthesis of 2‐Fluorinated C‐Glycosides
por: Sadurní, Anna, et al.
Publicado: (2018)

Polyketide stereocontrol: a study in chemical biology
por: Weissman, Kira J
Publicado: (2017)

Protecting group free glycosylation: one-pot stereocontrolled access to 1,2-trans glycosides and (1→6)-linked disaccharides of 2-acetamido sugars
por: Qiu, Xin, et al.
Publicado: (2022)

Independent Control of Elastomer Properties through Stereocontrolled Synthesis
por: Bell, Craig A., et al.
Publicado: (2016)

Cornforth–Evans Transition States in Stereocontrolled Allylborations of Epoxy Aldehydes
por: Freund, Robert R. A., et al.
Publicado: (2020)

A Dynamic Thermodynamic Resolution Strategy for the Stereocontrolled Synthesis of Streptonigrin
por: Valdez Pérez, Luis F., et al.
Publicado: (2022)

A thermo-reversible silicone elastomer with remotely controlled self-healing
por: Ogliani, E., et al.
Publicado: (2018)

Walking Metals for Remote Functionalization
por: Sommer, Heiko, et al.
Publicado: (2018)

A Stereocontrolled Protocol to Highly Functionalized Fluorinated Scaffolds through a Fluoride Opening of Oxiranes
por: Remete, Attila Márió, et al.
Publicado: (2016)

Cannot write session to /tmp/vufind_sessions/sess_nm25arqamfieavjno2no8jrkfj