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Manganese(II) complexes with Bn-tpen as powerful catalysts of cyclohexene oxidation
Manganese(II) complex [(Bn-tpen)Mn(II)](2+) activated dioxygen for oxidation of cyclohexene in acetonitrile (MeCN) and methanol (MeOH). In MeCN, ketone (2-cyclohexen-1-one), alcohol (2-cyclohexen-1-ol) and small amounts of epoxide (cyclohexene oxide) were produced in this reaction, while in MeOH onl...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Springer International Publishing
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5655609/ https://www.ncbi.nlm.nih.gov/pubmed/29104351 http://dx.doi.org/10.1007/s11696-017-0201-0 |