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Functionalization of P(4) through Direct P−C Bond Formation

Research on chlorine‐free conversions of P(4) into organophosphorus compounds (OPCs) has a long track record, but methods that allow desirable, direct P−C bond formations have only recently emerged. These include the use of metal organyls, carbenes, carboradicals, and photochemical approaches. The v...

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Detalles Bibliográficos
Autores principales: Borger, Jaap E., Ehlers, Andreas W., Slootweg, J. Chris, Lammertsma, Koop
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5655700/
https://www.ncbi.nlm.nih.gov/pubmed/28497639
http://dx.doi.org/10.1002/chem.201702067
Descripción
Sumario:Research on chlorine‐free conversions of P(4) into organophosphorus compounds (OPCs) has a long track record, but methods that allow desirable, direct P−C bond formations have only recently emerged. These include the use of metal organyls, carbenes, carboradicals, and photochemical approaches. The versatile product scope enables the preparation of both industrially relevant organophosphorus compounds, as well as a broad range of intriguing new compound classes. Herein we provide a concise overview of recent breakthroughs and outline the acquired fundamental insights to aid future developments.