Cargando…

Silver‐Catalyzed Stereoselective Aminosulfonylation of Alkynes

A silver‐catalyzed intermolecular aminosulfonylation of terminal alkynes with sodium sulfinates and TMSN(3) is reported. This three‐component reaction proceeds through sequential hydroazidation of the terminal alkyne and addition of a sulfonyl radical to the resultant vinyl azide. The method enables...

Descripción completa

Detalles Bibliográficos
Autores principales:	Ning, Yongquan, Ji, Qinghe, Liao, Peiqiu, Anderson, Edward A., Bi, Xihe
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2017
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5655761/ https://www.ncbi.nlm.nih.gov/pubmed/28627090 http://dx.doi.org/10.1002/anie.201705122

Ejemplares similares

Stereoselective cobalt-catalyzed halofluoroalkylation of alkynes
por: Wu, Guojiao, et al.
Publicado: (2018)

Silver-Catalyzed Regio- and Stereoselective Formal Carbene Insertion into Unstrained C−C σ-Bonds of 1,3-Dicarbonyls
por: Liu, Zhaohong, et al.
Publicado: (2018)

Stereoselective Gold(I)-Catalyzed Intermolecular Hydroalkoxlation of Alkynes
por: Veenboer, Richard M. P., et al.
Publicado: (2015)

Highly Efficient Gold(I)-Catalyzed Regio- and Stereoselective Hydrocarboxylation of Internal Alkynes
por: Dupuy, Stéphanie, et al.
Publicado: (2015)

Stereoselective Synthesis of Tertiary Allylic Amines by Titanium‐Catalyzed Hydroaminoalkylation of Alkynes with Tertiary Amines
por: Kaper, Tobias, et al.
Publicado: (2022)

Substrate-Controlled Cu(OAc)(2)-Catalyzed Stereoselective Semi-Reduction of Alkynes with MeOH as the Hydrogen Source
por: Huang, Jiuzhong, et al.
Publicado: (2021)

Cationic-palladium catalyzed regio- and stereoselective syn-1,2-dicarbofunctionalization of unsymmetrical internal alkynes
por: Dutta, Shubham, et al.
Publicado: (2022)

Photoinduced Palladium‐Catalyzed Dicarbofunctionalization of Terminal Alkynes
por: Yang, Zhen, et al.
Publicado: (2021)

Aluminium‐Catalyzed C(sp)−H Borylation of Alkynes
por: Willcox, Dominic R., et al.
Publicado: (2021)

Silver-catalyzed synthesis of β-fluorovinylphosphonates by phosphonofluorination of aromatic alkynes
por: Zhang, Yajing, et al.
Publicado: (2020)

Palladium‐Catalyzed Direct Stereoselective Synthesis of Deoxyglycosides from Glycals
por: Sau, Abhijit, et al.
Publicado: (2017)

Acid, silver, and solvent-free gold-catalyzed hydrophenoxylation of internal alkynes
por: Richard, Marcia E, et al.
Publicado: (2013)

Stereoselective synthesis of pentasubstituted 1,3-dienes via Ni-catalyzed reductive coupling of unsymmetrical internal alkynes
por: Zhou, Zhijun, et al.
Publicado: (2020)

Substrate-Controlled Product Divergence: Silver-Catalyzed Reaction of Trifluoromethyl Ketones with Terminal Alkynes
por: Li, Fang-Ling, et al.
Publicado: (2017)

Conditional Copper‐Catalyzed Azide–Alkyne Cycloaddition by Catalyst Encapsulation
por: Brevé, Tobias G., et al.
Publicado: (2020)

Iodine-promoted stereoselective amidosulfenylation of electron-deficient alkynes
por: Xiao, Fuhong, et al.
Publicado: (2018)

Crystal structure of 4-[(5-methylisoxazol-3-yl)aminosulfonyl]anilinium 3,5-dinitrosalicylate
por: Malathy, Sevaiyan, et al.
Publicado: (2015)

Alkyne-Azide Cycloaddition Catalyzed by Silver Chloride and “Abnormal” Silver N-Heterocyclic Carbene Complex
por: Ortega-Arizmendi, Aldo I., et al.
Publicado: (2013)

Olefin‐Directed Palladium‐Catalyzed Regio‐ and Stereoselective Oxidative Arylation of Allenes
por: Zhu, Can, et al.
Publicado: (2015)

Palladium‐Catalyzed Oxidative Synthesis of α‐Acetoxylated Enones from Alkynes
por: Jiang, Tuo, et al.
Publicado: (2016)

Enantio‐ and Diastereoselective Copper‐Catalyzed Allylboration of Alkynes with Allylic gem‐Dichlorides
por: Chaves‐Pouso, Andrea, et al.
Publicado: (2022)

Silver-catalyzed site-selective C(sp(3))−H benzylation of ethers with N-triftosylhydrazones
por: Liu, Zhaohong, et al.
Publicado: (2022)

Gold-Catalyzed Synthesis of Tetrazoles from Alkynes by C=C Bond Cleavage**
por: Gaydou, Morgane, et al.
Publicado: (2013)

Gold(I)‐Catalyzed Haloalkynylation of Aryl Alkynes: Two Pathways, One Goal
por: Kreuzahler, Mathis, et al.
Publicado: (2020)

Ruthenaelectro‐Catalyzed Domino Three‐Component Alkyne Annulation for Expedient Isoquinoline Assembly
por: Tan, Xuefeng, et al.
Publicado: (2021)

Reaction Pathways and Redox States in α‐Selective Cobalt‐Catalyzed Hydroborations of Alkynes
por: Blasius, Clemens K., et al.
Publicado: (2020)

Rhodium‐NHC‐Catalyzed gem‐Specific O‐Selective Hydropyridonation of Terminal Alkynes
por: Galiana‐Cameo, María, et al.
Publicado: (2022)

Rhodium-Catalyzed [2 + 2 + 2] Cyclotrimerizations of Yndiamides with Alkynes
por: Smith, Philip J., et al.
Publicado: (2022)

Iron-catalyzed carboazidation of alkenes and alkynes
por: Xiong, Haigen, et al.
Publicado: (2019)

2-Aminobenzaldehydes as Versatile Substrates for Rhodium-Catalyzed Alkyne Hydroacylation: Application to Dihydroquinolone Synthesis**
por: Castaing, Matthias, et al.
Publicado: (2013)

Highly Efficient Recyclable Sol Gel Polymer Catalyzed One Pot Difunctionalization of Alkynes
por: Domena, Justin, et al.
Publicado: (2018)

Synthesis of 2‐Alkynoates by Palladium(II)‐Catalyzed Oxidative Carbonylation of Terminal Alkynes and Alcohols
por: Cao, Qun, et al.
Publicado: (2016)

α‐Amidoaldehydes as Substrates in Rhodium‐Catalyzed Intermolecular Alkyne Hydroacylation: The Synthesis of α‐Amidoketones
por: Pal, Ritashree, et al.
Publicado: (2020)

Structural Determinants of Alkyne Reactivity in Copper-Catalyzed Azide-Alkyne Cycloadditions
por: Zhang, Xiaoguang, et al.
Publicado: (2016)

Stereoselective Promiscuous Reactions Catalyzed by Lipases
por: Patti, Angela, et al.
Publicado: (2022)

Rhodium(i)-catalyzed stereoselective [4+2] cycloaddition of oxetanols with alkynes through C(sp(3))–C(sp(3)) bond cleavage
por: Guo, Rui, et al.
Publicado: (2017)

Regio- and Stereoselective Allylindation of Alkynes Using InBr(3) and Allylic Silanes: Synthesis, Characterization, and Application of 1,4-Dienylindiums toward Skipped Dienes
por: Nishimoto, Yoshihiro, et al.
Publicado: (2018)

Regio- and Stereoselective Radical Perfluoroalkyltriflation of Alkynes Using Phenyl(perfluoroalkyl)iodonium Triflates
por: Wang, Xi, et al.
Publicado: (2017)

Polyhedral Cu(2)O to Cu pseudomorphic conversion for stereoselective alkyne semihydrogenation
por: Rej, Sourav, et al.
Publicado: (2018)

Regiocontrol in the cobalt-catalyzed hydrosilylation of alkynes
por: Wu, Guojiao, et al.
Publicado: (2018)

Cannot write session to /tmp/vufind_sessions/sess_lgqfv3gt45l9pm1nd101pluqbq