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Highly efficient hydrogenation of carbon dioxide to formate catalyzed by iridium(iii) complexes of imine–diphosphine ligands
A new iridium catalyst containing an imine–diphosphine ligand has been developed, which showed high efficiency for the hydrogenation of CO(2) to formate (yield up to 99%, TON up to 450 000). A possible catalytic mechanism is proposed, in which the imine group of the catalyst plays a key role in the...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2015
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5655897/ https://www.ncbi.nlm.nih.gov/pubmed/29308169 http://dx.doi.org/10.1039/c5sc00248f |