New Routes for Refinery of Biogenic Platform Chemicals Catalyzed by Cerium Oxide-supported Ruthenium Nanoparticles in Water

Highly selective hydrogenative carbon–carbon bond scission of biomass-derived platform oxygenates was achieved with a cerium oxide-supported ruthenium nanoparticle catalyst in water. The present catalyst enabled the selective cleavage of carbon–carbon σ bonds adjacent to carboxyl, ester, and hydroxy...

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Autores principales: Mizugaki, Tomoo, Togo, Keito, Maeno, Zen, Mitsudome, Takato, Jitsukawa, Koichiro, Kaneda, Kiyotomi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2017
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Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5656575/
https://www.ncbi.nlm.nih.gov/pubmed/29070900
http://dx.doi.org/10.1038/s41598-017-14373-1
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author Mizugaki, Tomoo
Togo, Keito
Maeno, Zen
Mitsudome, Takato
Jitsukawa, Koichiro
Kaneda, Kiyotomi
author_facet Mizugaki, Tomoo
Togo, Keito
Maeno, Zen
Mitsudome, Takato
Jitsukawa, Koichiro
Kaneda, Kiyotomi
author_sort Mizugaki, Tomoo
collection PubMed
description Highly selective hydrogenative carbon–carbon bond scission of biomass-derived platform oxygenates was achieved with a cerium oxide-supported ruthenium nanoparticle catalyst in water. The present catalyst enabled the selective cleavage of carbon–carbon σ bonds adjacent to carboxyl, ester, and hydroxymethyl groups, opening new eight synthetic routes to valuable chemicals from biomass derivatives. The high selectivity for such carbon-carbon bond scission over carbon-oxygen bonds was attributed to the multiple catalytic roles of the Ru nanoparticles assisted by the in situ formed Ce(OH)(3).
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spelling pubmed-56565752017-10-31 New Routes for Refinery of Biogenic Platform Chemicals Catalyzed by Cerium Oxide-supported Ruthenium Nanoparticles in Water Mizugaki, Tomoo Togo, Keito Maeno, Zen Mitsudome, Takato Jitsukawa, Koichiro Kaneda, Kiyotomi Sci Rep Article Highly selective hydrogenative carbon–carbon bond scission of biomass-derived platform oxygenates was achieved with a cerium oxide-supported ruthenium nanoparticle catalyst in water. The present catalyst enabled the selective cleavage of carbon–carbon σ bonds adjacent to carboxyl, ester, and hydroxymethyl groups, opening new eight synthetic routes to valuable chemicals from biomass derivatives. The high selectivity for such carbon-carbon bond scission over carbon-oxygen bonds was attributed to the multiple catalytic roles of the Ru nanoparticles assisted by the in situ formed Ce(OH)(3). Nature Publishing Group UK 2017-10-25 /pmc/articles/PMC5656575/ /pubmed/29070900 http://dx.doi.org/10.1038/s41598-017-14373-1 Text en © The Author(s) 2017 Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.
spellingShingle Article
Mizugaki, Tomoo
Togo, Keito
Maeno, Zen
Mitsudome, Takato
Jitsukawa, Koichiro
Kaneda, Kiyotomi
New Routes for Refinery of Biogenic Platform Chemicals Catalyzed by Cerium Oxide-supported Ruthenium Nanoparticles in Water
title New Routes for Refinery of Biogenic Platform Chemicals Catalyzed by Cerium Oxide-supported Ruthenium Nanoparticles in Water
title_full New Routes for Refinery of Biogenic Platform Chemicals Catalyzed by Cerium Oxide-supported Ruthenium Nanoparticles in Water
title_fullStr New Routes for Refinery of Biogenic Platform Chemicals Catalyzed by Cerium Oxide-supported Ruthenium Nanoparticles in Water
title_full_unstemmed New Routes for Refinery of Biogenic Platform Chemicals Catalyzed by Cerium Oxide-supported Ruthenium Nanoparticles in Water
title_short New Routes for Refinery of Biogenic Platform Chemicals Catalyzed by Cerium Oxide-supported Ruthenium Nanoparticles in Water
title_sort new routes for refinery of biogenic platform chemicals catalyzed by cerium oxide-supported ruthenium nanoparticles in water
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5656575/
https://www.ncbi.nlm.nih.gov/pubmed/29070900
http://dx.doi.org/10.1038/s41598-017-14373-1
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