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Dynamic Covalent Chemistry of Aldehyde Enamines: Bi(III)‐ and Sc(III)‐Catalysis of Amine–Enamine Exchange

The dynamic exchange of enamines from secondary amines and enolizable aldehydes has been demonstrated in organic solvents. The enamine exchange with amines was efficiently catalyzed by Bi(OTf)(3) and Sc(OTf)(3) (2 mol %) and the equilibria (60 mm) could be attained within hours at room temperature....

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Detalles Bibliográficos
Autores principales: Zhang, Yang, Xie, Sheng, Yan, Mingdi, Ramström, Olof
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5656824/
https://www.ncbi.nlm.nih.gov/pubmed/28722305
http://dx.doi.org/10.1002/chem.201702363

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