Transition‐Metal‐Free Cleavage of CO

Tertiary silane 1(H), 2‐[(diphenylsilyl)methyl]‐6‐methylpyridine, reacts with tris(pentafluorophenyl)borane (BCF) to form the intramolecular pyridine‐stabilized silylium 1(+)‐HBCF. The corresponding 2‐[(diphenylsilyl)methyl]pyridine, lacking the methyl‐group on the pyridine ring, forms classic N(py)...

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Detalles Bibliográficos
Autores principales: Devillard, Marc, de Bruin, Bas, Siegler, Maxime A., van der Vlugt, J. I.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2017
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5656908/
https://www.ncbi.nlm.nih.gov/pubmed/28816371
http://dx.doi.org/10.1002/chem.201703798

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5656908/
https://www.ncbi.nlm.nih.gov/pubmed/28816371
http://dx.doi.org/10.1002/chem.201703798

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