Cargando…
meta‐Selective C−H Borylation of Benzylamine‐, Phenethylamine‐, and Phenylpropylamine‐Derived Amides Enabled by a Single Anionic Ligand
Selective functionalization at the meta position of arenes remains a significant challenge. In this work, we demonstrate that a single anionic bipyridine ligand bearing a remote sulfonate group enables selective iridium‐catalyzed borylation of a range of common amine‐containing aromatic molecules at...
Autores principales: | Davis, Holly J., Genov, Georgi R., Phipps, Robert J. |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2017
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5656929/ https://www.ncbi.nlm.nih.gov/pubmed/28877397 http://dx.doi.org/10.1002/anie.201708967 |
Ejemplares similares
-
Interrogating the
Crucial Interactions at Play in
the Chiral Cation-Directed Enantioselective Borylation of Arenes
por: Ermanis, Kristaps, et al.
Publicado: (2023) -
Approaching a “Naked” Boryl Anion: Amide Metathesis as a Route to Calcium, Strontium, and Potassium Boryl Complexes
por: Protchenko, Andrey V., et al.
Publicado: (2020) -
A tautomerized ligand enabled meta selective C–H borylation of phenol
por: Guria, Saikat, et al.
Publicado: (2023) -
NNB-Type Tridentate Boryl Ligands Enabling a Highly Active Iridium Catalyst for C–H Borylation
por: Ding, Siyi, et al.
Publicado: (2019) -
Strain-release 2-azaallyl anion addition/borylation of [1.1.1]propellane: synthesis and functionalization of benzylamine bicyclo[1.1.1]pentyl boronates
por: Shelp, Russell A., et al.
Publicado: (2021)