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Self-organisation of dodeca-dendronized fullerene into supramolecular discs and helical columns containing a nanowire-like core
Twelve chiral and achiral self-assembling dendrons have been grafted onto a [60]fullerene hexa-adduct core by copper-catalyzed alkyne azide “click” cycloaddition. The structure adopted by these compounds was determined by the self-assembling peripheral dendrons. These twelve dendrons mediate the sel...
Autores principales: | , , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5657094/ https://www.ncbi.nlm.nih.gov/pubmed/29142695 http://dx.doi.org/10.1039/c5sc00449g |
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author | Guerra, Sebastiano Iehl, Julien Holler, Michel Peterca, Mihai Wilson, Daniela A. Partridge, Benjamin E. Zhang, Shaodong Deschenaux, Robert Nierengarten, Jean-François Percec, Virgil |
author_facet | Guerra, Sebastiano Iehl, Julien Holler, Michel Peterca, Mihai Wilson, Daniela A. Partridge, Benjamin E. Zhang, Shaodong Deschenaux, Robert Nierengarten, Jean-François Percec, Virgil |
author_sort | Guerra, Sebastiano |
collection | PubMed |
description | Twelve chiral and achiral self-assembling dendrons have been grafted onto a [60]fullerene hexa-adduct core by copper-catalyzed alkyne azide “click” cycloaddition. The structure adopted by these compounds was determined by the self-assembling peripheral dendrons. These twelve dendrons mediate the self-organisation of the dendronized [60]fullerene into a disc-shaped structure containing the [60]fullerene in the centre. The fullerene-containing discs self-organise into helical supramolecular columns with a fullerene nanowire-like core, forming a 2D columnar hexagonal periodic array. These unprecedented supramolecular structures and their assemblies are expected to provide new developments in chiral complex molecular systems and their application to organic electronics and solar cells. |
format | Online Article Text |
id | pubmed-5657094 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2015 |
publisher | Royal Society of Chemistry |
record_format | MEDLINE/PubMed |
spelling | pubmed-56570942017-11-15 Self-organisation of dodeca-dendronized fullerene into supramolecular discs and helical columns containing a nanowire-like core Guerra, Sebastiano Iehl, Julien Holler, Michel Peterca, Mihai Wilson, Daniela A. Partridge, Benjamin E. Zhang, Shaodong Deschenaux, Robert Nierengarten, Jean-François Percec, Virgil Chem Sci Chemistry Twelve chiral and achiral self-assembling dendrons have been grafted onto a [60]fullerene hexa-adduct core by copper-catalyzed alkyne azide “click” cycloaddition. The structure adopted by these compounds was determined by the self-assembling peripheral dendrons. These twelve dendrons mediate the self-organisation of the dendronized [60]fullerene into a disc-shaped structure containing the [60]fullerene in the centre. The fullerene-containing discs self-organise into helical supramolecular columns with a fullerene nanowire-like core, forming a 2D columnar hexagonal periodic array. These unprecedented supramolecular structures and their assemblies are expected to provide new developments in chiral complex molecular systems and their application to organic electronics and solar cells. Royal Society of Chemistry 2015-06-01 2015-04-09 /pmc/articles/PMC5657094/ /pubmed/29142695 http://dx.doi.org/10.1039/c5sc00449g Text en This journal is © The Royal Society of Chemistry 2015 http://creativecommons.org/licenses/by/3.0/ This is an Open Access article distributed under the terms of the Creative Commons Attribution 3.0 Unported License (http://creativecommons.org/licenses/by/3.0/) which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. |
spellingShingle | Chemistry Guerra, Sebastiano Iehl, Julien Holler, Michel Peterca, Mihai Wilson, Daniela A. Partridge, Benjamin E. Zhang, Shaodong Deschenaux, Robert Nierengarten, Jean-François Percec, Virgil Self-organisation of dodeca-dendronized fullerene into supramolecular discs and helical columns containing a nanowire-like core |
title | Self-organisation of dodeca-dendronized fullerene into supramolecular discs and helical columns containing a nanowire-like core
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title_full | Self-organisation of dodeca-dendronized fullerene into supramolecular discs and helical columns containing a nanowire-like core
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title_fullStr | Self-organisation of dodeca-dendronized fullerene into supramolecular discs and helical columns containing a nanowire-like core
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title_full_unstemmed | Self-organisation of dodeca-dendronized fullerene into supramolecular discs and helical columns containing a nanowire-like core
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title_short | Self-organisation of dodeca-dendronized fullerene into supramolecular discs and helical columns containing a nanowire-like core
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title_sort | self-organisation of dodeca-dendronized fullerene into supramolecular discs and helical columns containing a nanowire-like core |
topic | Chemistry |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5657094/ https://www.ncbi.nlm.nih.gov/pubmed/29142695 http://dx.doi.org/10.1039/c5sc00449g |
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