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Pd-catalyzed asymmetric hydrogenation of fluorinated aromatic pyrazol-5-ols via capture of active tautomers
An efficient palladium-catalyzed asymmetric hydrogenation of fluorinated aromatic pyrazol-5-ols has been developed via capture of the active tautomers. A wide variety of 2,5-disubstituted and 2,4,5-trisubstituted pyrazolidinones have been synthesized with up to 96% and 95% ee, respectively. The hydr...
Autores principales: | Chen, Zhang-Pei, Chen, Mu-Wang, Shi, Lei, Yu, Chang-Bin, Zhou, Yong-Gui |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5659069/ https://www.ncbi.nlm.nih.gov/pubmed/29511507 http://dx.doi.org/10.1039/c5sc00835b |
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