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Enantioselective and diastereoselective azo-coupling/iminium-cyclizations: a unified strategy for the total syntheses of (–)-psychotriasine and (+)-pestalazine B

We report a unified strategy for the total syntheses of (–)-psychotriasine and (+)-pestalazine B based on the advanced intermediates of 3α-amino-hexahydropyrrolo[2,3-b]indole. To construct these structural motifs, a cascade reaction involving a BINOL-derived phosphoric anion-paired catalyst for enan...

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Detalles Bibliográficos
Autores principales:	Li, Qi, Xia, Tingting, Yao, Licheng, Deng, Haiteng, Liao, Xuebin
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2015
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5659145/ https://www.ncbi.nlm.nih.gov/pubmed/29511522 http://dx.doi.org/10.1039/c5sc00338e

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