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Asymmetric C–H functionalization of cyclopropanes using an isoleucine-NH(2) bidentate directing group

The systematic investigation of substrate-bound α-amino acid auxiliaries has resulted in catalytic asymmetric C–H functionalization of cyclopropanes enabled by amino acid amides as chiral bidentate directing groups. The use of an Ile-NH(2) auxiliary embedded in the substrate provided excellent level...

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Detalles Bibliográficos
Autores principales:	Kim, Jinhee, Sim, Mikyung, Kim, Namhoon, Hong, Sungwoo
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2015
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5659170/ https://www.ncbi.nlm.nih.gov/pubmed/29511524 http://dx.doi.org/10.1039/c5sc01137j

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