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Fluoride binding to an organoboron wire controls photoinduced electron transfer
We demonstrate that the rates for long-range electron transfer can be controlled actively by tight anion binding to a rigid rod-like molecular bridge. Electron transfer from a triarylamine donor to a photoexcited Ru(bpy)(3)(2+) acceptor (bpy = 2,2′-bipyridine) across a 2,5-diboryl-1,4-phenylene brid...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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Royal Society of Chemistry
2015
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5659175/ https://www.ncbi.nlm.nih.gov/pubmed/29511520 http://dx.doi.org/10.1039/c5sc00964b |