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Mixed-ligand complexes of paddlewheel dinuclear molybdenum as hydrodehalogenation catalysts for polyhaloalkanes

We developed a hydrodehalogenation reaction of polyhaloalkanes catalyzed by paddlewheel dimolybdenum complexes in combination with 1-methyl-3,6-bis(trimethylsilyl)-1,4-cyclohexadiene (MBTCD) as a non-toxic H-atom source as well as a salt-free reductant. A mixed-ligated dimolybdenum complex Mo(2)(OAc...

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Detalles Bibliográficos
Autores principales:	Tsurugi, Hayato, Hayakawa, Akio, Kando, Shun, Sugino, Yoshitaka, Mashima, Kazushi
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2015
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5659211/ https://www.ncbi.nlm.nih.gov/pubmed/29511508 http://dx.doi.org/10.1039/c5sc00721f

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