Metal influence on the iso- and hetero-selectivity of complexes of bipyrrolidine derived salan ligands for the polymerisation of rac-lactide

In this paper we have prepared a series of Ti(iv), Hf(iv) and Al(iii) complexes based on bipyrrolidine salan pro-ligands. The Hf(iv) complexes have all been characterised in the solid-state, the chiral ligands coordinate to Hf(iv) in an α-cis manner whereas the meso ligand coordinates in a β-cis geo...

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Detalles Bibliográficos
Autores principales: Jones, Matthew D., Brady, Lauren, McKeown, Paul, Buchard, Antoine, Schäfer, Pascal M., Thomas, Lynne H., Mahon, Mary F., Woodman, Timothy J., Lowe, John P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5664169/
https://www.ncbi.nlm.nih.gov/pubmed/29142728
http://dx.doi.org/10.1039/c5sc01819f

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