Bioinspired design of redox-active ligands for multielectron catalysis: effects of positioning pyrazine reservoirs on cobalt for electro- and photocatalytic generation of hydrogen from water

Mononuclear metalloenzymes in nature can function in cooperation with precisely positioned redox-active organic cofactors in order to carry out multielectron catalysis. Inspired by the finely tuned redox management of these bioinorganic systems, we present the design, synthesis, and experimental and...

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Detalles Bibliográficos
Autores principales: Jurss, Jonah W., Khnayzer, Rony S., Panetier, Julien A., El Roz, Karim A., Nichols, Eva M., Head-Gordon, Martin, Long, Jeffrey R., Castellano, Felix N., Chang, Christopher J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5664355/
https://www.ncbi.nlm.nih.gov/pubmed/29142725
http://dx.doi.org/10.1039/c5sc01414j

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