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C–H bond activation induced by thorium metallacyclopropene complexes: a combined experimental and computational study

Inter- and intramolecular C–H bond activations by thorium metallacyclopropene complexes were comprehensively studied. The reduction of [η(5)-1,2,4-(Me(3)C)(3)C(5)H(2)](2)ThCl(2) (1) with potassium graphite (KC(8)) in the presence of internal alkynes (PhC[triple bond, length as m-dash]CR) yields the...

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Detalles Bibliográficos
Autores principales:	Fang, Bo, Zhang, Lei, Hou, Guohua, Zi, Guofu, Fang, De-Cai, Walter, Marc D.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2015
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5664364/ https://www.ncbi.nlm.nih.gov/pubmed/29142721 http://dx.doi.org/10.1039/c5sc01684c

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