Enhancing electron affinity and tuning band gap in donor–acceptor organic semiconductors by benzothiadiazole directed C–H borylation

Electrophilic borylation using BCl(3) and benzothiadiazole to direct the C–H functionalisation of an adjacent aromatic unit produces fused boracyclic materials with minimally changed HOMO energy levels but significantly reduced LUMO energy levels. In situ alkylation and arylation at boron using Al(a...

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Detalles Bibliográficos
Autores principales: Crossley, D. L., Cade, I. A., Clark, E. R., Escande, A., Humphries, M. J., King, S. M., Vitorica-Yrezabal, I., Ingleson, M. J., Turner, M. L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5666683/
https://www.ncbi.nlm.nih.gov/pubmed/29142733
http://dx.doi.org/10.1039/c5sc01800e

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