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Reaction-activated palladium catalyst for dehydrogenation of substituted cyclohexanones to phenols and H(2) without oxidants and hydrogen acceptors

It is widely believed that the dehydrogenation of organic compounds is a thermodynamically unfavorable process, and thus requires stoichiometric oxidants such as dioxygen and metal oxides or sacrificial hydrogen acceptors to remove the hydrogen from the reaction mixture to drive the equilibrium towa...

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Detalhes bibliográficos
Principais autores: Zhang, Jingwu, Jiang, Qiangqiang, Yang, Dejun, Zhao, Xiaomei, Dong, Yanli, Liu, Renhua
Formato: Online Atigo Texto
Idioma:English
Publicado em: Royal Society of Chemistry 2015
Assuntos:
Acesso em linha:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5667403/
https://www.ncbi.nlm.nih.gov/pubmed/29142706
http://dx.doi.org/10.1039/c5sc01044f