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Fe(iv) alkylidenes via protonation of Fe(ii) vinyl chelates and a comparative Mössbauer spectroscopic study

Treatment of cis-Me(2)Fe(PMe(3))(4) with di-1,2-(E-2-(pyridin-2-yl)vinyl)benzene ((bdvp)H(2)), a tetradentate ligand precursor, afforded (bdvp)Fe(PMe(3))(2) (1-PMe(3)) and 2 equiv. CH(4), via C–H bond activation. Similar treatments with tridentate ligand precursors PhCH[double bond, length as m-dash...

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Detalles Bibliográficos
Autores principales:	Lindley, Brian M., Swidan, Ala'aeddeen, Lobkovsky, Emil B., Wolczanski, Peter T., Adelhardt, Mario, Sutter, Jörg, Meyer, Karsten
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2015
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5667503/ https://www.ncbi.nlm.nih.gov/pubmed/29142710 http://dx.doi.org/10.1039/c5sc01268f

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