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Conjugated nitrosoalkenes as Michael acceptors in carbon–carbon bond forming reactions: a review and perspective

Despite of their chemical instability and high reactivity, conjugated nitrosoalkenes are useful intermediates in target-oriented organic synthesis. The present review deals with carbon–carbon bond forming reactions involving Michael addition to α-nitrosoalkenes with a particular focus on recent deve...

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Autores principales: Boyko, Yaroslav Dmitrievich, Dorokhov, Valentin Sergeevich, Sukhorukov, Alexey Yu, Ioffe, Sema Leibovich
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5669230/
https://www.ncbi.nlm.nih.gov/pubmed/29114327
http://dx.doi.org/10.3762/bjoc.13.220
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author Boyko, Yaroslav Dmitrievich
Dorokhov, Valentin Sergeevich
Sukhorukov, Alexey Yu
Ioffe, Sema Leibovich
author_facet Boyko, Yaroslav Dmitrievich
Dorokhov, Valentin Sergeevich
Sukhorukov, Alexey Yu
Ioffe, Sema Leibovich
author_sort Boyko, Yaroslav Dmitrievich
collection PubMed
description Despite of their chemical instability and high reactivity, conjugated nitrosoalkenes are useful intermediates in target-oriented organic synthesis. The present review deals with carbon–carbon bond forming reactions involving Michael addition to α-nitrosoalkenes with a particular focus on recent developments in this methodology and its use in total synthesis.
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spelling pubmed-56692302017-11-07 Conjugated nitrosoalkenes as Michael acceptors in carbon–carbon bond forming reactions: a review and perspective Boyko, Yaroslav Dmitrievich Dorokhov, Valentin Sergeevich Sukhorukov, Alexey Yu Ioffe, Sema Leibovich Beilstein J Org Chem Review Despite of their chemical instability and high reactivity, conjugated nitrosoalkenes are useful intermediates in target-oriented organic synthesis. The present review deals with carbon–carbon bond forming reactions involving Michael addition to α-nitrosoalkenes with a particular focus on recent developments in this methodology and its use in total synthesis. Beilstein-Institut 2017-10-23 /pmc/articles/PMC5669230/ /pubmed/29114327 http://dx.doi.org/10.3762/bjoc.13.220 Text en Copyright © 2017, Boyko et al. https://creativecommons.org/licenses/by/4.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/4.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Review
Boyko, Yaroslav Dmitrievich
Dorokhov, Valentin Sergeevich
Sukhorukov, Alexey Yu
Ioffe, Sema Leibovich
Conjugated nitrosoalkenes as Michael acceptors in carbon–carbon bond forming reactions: a review and perspective
title Conjugated nitrosoalkenes as Michael acceptors in carbon–carbon bond forming reactions: a review and perspective
title_full Conjugated nitrosoalkenes as Michael acceptors in carbon–carbon bond forming reactions: a review and perspective
title_fullStr Conjugated nitrosoalkenes as Michael acceptors in carbon–carbon bond forming reactions: a review and perspective
title_full_unstemmed Conjugated nitrosoalkenes as Michael acceptors in carbon–carbon bond forming reactions: a review and perspective
title_short Conjugated nitrosoalkenes as Michael acceptors in carbon–carbon bond forming reactions: a review and perspective
title_sort conjugated nitrosoalkenes as michael acceptors in carbon–carbon bond forming reactions: a review and perspective
topic Review
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5669230/
https://www.ncbi.nlm.nih.gov/pubmed/29114327
http://dx.doi.org/10.3762/bjoc.13.220
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