Coordination diversity in hydrogen-bonded homoleptic fluoride–alcohol complexes modulates reactivity

The nucleophilic reactivity of fluoride ion is altered in the presence of hydrogen-bond donors, including alcohols. Relatively little is known about the coordination involved; to rectify this, the X-ray structures of fourteen novel fluoride–alcohol complexes with tetrabutylammonium as the counterion...

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Detalles Bibliográficos
Autores principales: Engle, Keary M., Pfeifer, Lukas, Pidgeon, George W., Giuffredi, Guy T., Thompson, Amber L., Paton, Robert S., Brown, John M., Gouverneur, Véronique
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5669313/
https://www.ncbi.nlm.nih.gov/pubmed/29449931
http://dx.doi.org/10.1039/c5sc01812a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5669313/
https://www.ncbi.nlm.nih.gov/pubmed/29449931
http://dx.doi.org/10.1039/c5sc01812a

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